y using a cerium-oxide-supported gold nanoparticle catalyst, we have achieved a highly difficult reaction that breaks through conventional selectivity and produces meta-phenylenediamines from cyclohexenones and secondary amines.
【MS title】
Au-Catalyzed Aerobic Dehydrogenative Aromatization to m-Phenylenediamine Derivatives via Product Selectivity Control
【Authors】
Heizo Kimura, Takafumi Yatabe, Kazuya Yamaguchi
【Journal】
J. Am. Chem. Soc.
DOI：10.1021/jacs.4c12043
URL：https://doi.org/10.1021/jacs.4c12043
【Press release】
https://www.t.u-tokyo.ac.jp/press/pr2025-07-25-001
